Antimony oxides: the pyrochlore-type structure revisited
نویسندگان
چکیده
منابع مشابه
Magnetic pyrochlore oxides
Within the past 20 years or so, there has occurred an explosion of interest in the magnetic behavior of pyrochlore oxides of the type A 2 B 4+ 2 O7 where A is a rare-earth ion and B is usually a transition metal. Both the A and B sites form a network of corner-sharing tetrahedra which is the quintessential framework for a geometrically frustrated magnet. In these systems the natural tendency to...
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where t is the transfer integral for nearest-neighbor sites hiji on the pyrochlore lattice, JH represents the Hund’s-rule coupling between the itinerant electron spin ~si and the localized spin ~ Si, while JAF is the super-exchange antiferromagnetic interaction between the neighboring localized spins. The first two terms induce the double-exchange ferromagnetic interactions through the kinetic ...
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We describe the ferromagnetism in the manganese pyrochlores, such as Tl2Mn2O7 and Sc2Mn2O7 , in terms of the interplay between superexchange, Zener double exchange, and indirect exchange, the first being antiferromagnetic ~AF! while the last two are ferromagnetic. The tendency towards the antiferroalignment of the localized Mn spins is significantly weakened due to ~i! the presence of spin frus...
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The centrosymmetric structure of Co2Al9 (space group P21/c, Pearson symbol mP22), the isotypic structures of Rh2Al9 and Ir2Al9 and the slightly distorted acentric structures of Rh2Ga9 and Ir2Ga9 (space group Pc) were reinvestigated from single crystal X-ray diffraction data. The structure of Rh2Ga9 represents a new structure type. The difference between the aluminides and the galDer Strukturtyp...
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Praseodymium calcium dimolybdenum hepta-oxide, Pr(1.37)Ca(0.63)Mo(2)O(7), crystallizes in the cubic pyrochlore-type structure. In the crystal structure, MoO(6) octa-hedra are linked together by common corners, forming a three-dimensional [Mo(2)O(6)] network. The Pr and Ca atoms and the remaining O atoms are located in the voids of the [Mo(2)O(6)] network. The Pr and Ca atoms are distributed sta...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section A Foundations of Crystallography
سال: 2005
ISSN: 0108-7673
DOI: 10.1107/s0108767305079523